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The synthesis and evaluation of a new anion receptor based on the 4-amido-1,8-naphthalimide scaffold is described. The findings indicate that the amide N–H is an enhanced H-bond donor but is otherwise restricted in its ability to participate in the binding of simple anions.

Graphical abstract: Comparing the anion binding of 4-amido- with 4-amino-1,8-naphthalimides

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