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Molybdenum disulfide (MoS2)–multiwalled carbon nanotube (MWCNT) hybrids have been prepared by simple dry grinding. Excellent initial charge capacity (1214 mA h g−1) and ∼85% retention after 60 discharge–charge cycles at different current densities (100–500 mA g−1) make MoS2–MWCNT (1 : 1) hybrids a superior anode in Li-ion batteries.