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The adsorption of benzene by CuBTC and MIL101(Cr) is investigated. The differences between both materials are discussed in terms of porous volume and affinities, determined by calculating Henry's constants and by measuring the adsorption enthalpies. If MIL101(Cr) adsorbs higher quantities of benzene, CuBTC develops stronger interaction, interesting for VOC remediation.

Graphical abstract: Comparison of the benzene sorption properties of metal organic frameworks: influence of the textural properties

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