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Enantioselective photoreaction has been a synthetic challenge for decades. With the continuous development of modern visible light photocatalysis and asymmetric catalysis, remarkable advances have been achieved through the synergistic action of these catalytic reactions, allowing the construction of various enantiomerically enriched molecules that were once inaccessible using photocatalytic reactions. This review presents some of the contemporary developments in enantioselective visible-light photocatalysis reactions, covering the period from 2008 to March 2020, with the contents classified by catalysis type.

Graphical abstract: Enantioselective synthesis enabled by visible light photocatalysis

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