Issue 7, 2015

Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters

Abstract

An efficient catalytic enantioselective Nazarov cyclization of divinyl ketoesters was developed using a chiral BOX/Cu(II) complex, which provides facile access to a variety of optically active multi-substituted cyclopent-2-enone esters in 78–95% yields with 78–90% ee.

Graphical abstract: Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters

Supplementary files

Article information

Article type
Research Article
Submitted
26 Cig 2015
Accepted
28 Agd 2015
First published
29 Agd 2015

Org. Chem. Front., 2015,2, 811-814

Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters

Z. Xu, H. Ren, L. Wang and Y. Tang, Org. Chem. Front., 2015, 2, 811 DOI: 10.1039/C5QO00099H

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