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Abstract | Cited by

Synthetic transformation of D-xylose into a four-membered cyclic ether allows for reactions with carbon dioxide (CO2) leading to linear polycarbonates by either a one-step ring-opening copolymerisation (ROCOP) directly, or by sequential isolation of a preformed six-membered cyclic carbonate followed by ring-opening polymerisation (ROP).

Graphical abstract: Sustainable synthesis of CO2-derived polycarbonates from d-xylose

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