Issue 43, 2022

cis-Dipyridyl porphyrin-based multicomponent organoplatinum(ii) bismetallacycles for photocatalytic oxidation

Abstract

Three porphyrin-based bismetallacycles are prepared via multi-component metal-coordination-driven self-assembly. Owing to different tetracarboxylic ligands in their structures, they show distinct coordination geometries and stacking modes, which inhibit the self-aggregation of porphyrin and offer improved singlet oxygen generation efficiency. These bismetallacycles are successfully used for the photooxidation of methyl(phenyl)sulfane, showing their potential applications toward photocatalysis.

Graphical abstract: cis-Dipyridyl porphyrin-based multicomponent organoplatinum(ii) bismetallacycles for photocatalytic oxidation

Supplementary files

Article information

Article type
Paper
Submitted
08 Qad 2022
Accepted
11 Dit 2022
First published
12 Dit 2022

Dalton Trans., 2022,51, 16517-16521

cis-Dipyridyl porphyrin-based multicomponent organoplatinum(II) bismetallacycles for photocatalytic oxidation

Y. Cheng, Z. Zhang, X. Duan and M. Zhang, Dalton Trans., 2022, 51, 16517 DOI: 10.1039/D2DT02197H

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