Issue 16, 2023

Synthesis of triarylborane-centered N-heterocyclic carbene cages with tunable photophysical properties

Abstract

Triarylborane-based discrete metal-carbene supramolecular cages [M3(1)2](PF6)3 (M = Ag, Au) were synthesized and characterized. The new hexacarbene assemblies show a significant solvatochromic effect in solvents of different polarity. Furthermore, the reversible fluoride binding property of [Au3(1)2](PF6)3 was investigated by UV-vis absorption and fluorescence titrations. This work holds promise for future developments in the area of highly emissive and stimulus-responsive NHC-metal assemblies.

Graphical abstract: Synthesis of triarylborane-centered N-heterocyclic carbene cages with tunable photophysical properties

Supplementary files

Article information

Article type
Communication
Submitted
02 Kax 2022
Accepted
30 Qun 2023
First published
30 Qun 2023

Chem. Commun., 2023,59, 2291-2294

Synthesis of triarylborane-centered N-heterocyclic carbene cages with tunable photophysical properties

Y. Zhang, Y. Zhang, X. Li, L. Sun and Y. Han, Chem. Commun., 2023, 59, 2291 DOI: 10.1039/D2CC06584C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements