Issue 12, 2023

Water-based 2-dimensional anatase TiO2 inks for printed diodes and transistors

Abstract

2-Dimensional (2D) materials are attracting strong interest in printed electronics because of their unique properties and easy processability, enabling the fabrication of devices with low cost and mass scalable methods such as inkjet printing. For the fabrication of fully printed devices, it is of fundamental importance to develop a printable dielectric ink, providing good insulation and the ability to withstand large electric fields. Hexagonal boron nitride (h-BN) is typically used as a dielectric in printed devices. However, the h-BN film thickness is usually above 1 μm, hence limiting the use of h-BN in low-voltage applications. Furthermore, the h-BN ink is composed of nanosheets with broad lateral size and thickness distributions, due to the use of liquid-phase exfoliation (LPE). In this work, we investigate anatase TiO2 nanosheets (TiO2-NS), produced by a mass scalable bottom-up approach. We formulate the TiO2-NS into a water-based and printable solvent and demonstrate the use of the material with sub-micron thickness in printed diodes and transistors, hence validating the strong potential of TiO2-NS as a dielectric for printed electronics.

Graphical abstract: Water-based 2-dimensional anatase TiO2 inks for printed diodes and transistors

Supplementary files

Article information

Article type
Paper
Submitted
18 Dit 2022
Accepted
03 Nah 2023
First published
16 Nah 2023
This article is Open Access
Creative Commons BY-NC license

Nanoscale, 2023,15, 5689-5695

Water-based 2-dimensional anatase TiO2 inks for printed diodes and transistors

O. Kassem, L. Pimpolari, C. Dun, D. K. Polyushkin, M. Zarattini, E. Dimaggio, L. Chen, G. Basso, F. Parenti, J. J. Urban, T. Mueller, G. Fiori and C. Casiraghi, Nanoscale, 2023, 15, 5689 DOI: 10.1039/D2NR05786G

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements