Issue 2, 2015

Cationic Pd(ii)-catalyzed cyclization of N-tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives

Abstract

A cationic Pd(II)-catalyzed intramolecular alkyne-carbonyl reductive coupling reaction of N-tosyl-aniline tethered alkynyl ketones under transfer hydrogenation conditions to give hydroquinolines is developed.

Graphical abstract: Cationic Pd(ii)-catalyzed cyclization of N-tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives

Supplementary files

Article information

Article type
Research Article
Submitted
03 Xim 2014
Accepted
24 Kax 2014
First published
26 Kax 2014

Org. Chem. Front., 2015,2, 145-149

Cationic Pd(II)-catalyzed cyclization of N-tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives

K. Shen, X. Han, G. Xia and X. Lu, Org. Chem. Front., 2015, 2, 145 DOI: 10.1039/C4QO00286E

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