Issue 4, 2015

Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4] catalyst

Abstract

A Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using a well-defined aluminum porphyrin catalyst is reported. This reaction shows good functional group tolerance under mild reaction conditions to selectively give methyl ketones in excellent yields.

Graphical abstract: Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4]− catalyst

Supplementary files

Article information

Article type
Research Article
Submitted
12 Kax 2014
Accepted
31 Qun 2015
First published
16 Nah 2015

Org. Chem. Front., 2015,2, 346-349

Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4] catalyst

J. R. Lamb, Y. Jung and G. W. Coates, Org. Chem. Front., 2015, 2, 346 DOI: 10.1039/C4QO00324A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements