Issue 10, 2016

Assessment of the energetic performances of various ZIFs with SOD or RHO topology using high pressure water intrusion–extrusion experiments

Abstract

The energetic performances of seven SOD or RHO-topology ZIFs, with zinc or cobalt metal cation (ZIF-8, ZIF-90, Zn(dcim)2-SALE, ZIF-67, ZIF-7, ZIF-71, ZIF-11) were evaluated using water intrusion–extrusion under high pressure. The relationship between the structural parameters (in particular the pore system SOD or RHO, the type of linker, the metal cation nature) and the intrusion pressure was studied to better understand the mechanism of water intrusion and the energetic behaviour for a given ZIF crystal type. “ZIF-8–water”, “ZIF-67–water” and “ZIF-71–water” systems display a shock-absorber behaviour. A very important hysteresis for ZIF-71 and a slight difference between the first intrusion–extrusion cycle and the following ones for ZIF-67 were observed. ZIF-8 (SOD) with zinc cation and ZIF-67 (SOD) with cobalt cation display similar intrusion pressures. For ZIF-71 (RHO) material, the stored energy is more than doubled compared to ZIF-8 and ZIF-67 (SOD). This might be related to the topology. No water intrusion was observed after three water intrusion–extrusion cycles, for the ZIF-90 (SOD), Zn(dcim)2-SALE (SOD), ZIF-7 (SOD) and ZIF-11 (RHO) materials. This is explained in term of hydrophilic feature as well as topology and linker effects.

Graphical abstract: Assessment of the energetic performances of various ZIFs with SOD or RHO topology using high pressure water intrusion–extrusion experiments

Supplementary files

Article information

Article type
Paper
Submitted
07 Way 2015
Accepted
15 Qun 2016
First published
15 Qun 2016

Dalton Trans., 2016,45, 4392-4400

Assessment of the energetic performances of various ZIFs with SOD or RHO topology using high pressure water intrusion–extrusion experiments

I. Khay, G. Chaplais, H. Nouali, G. Ortiz, C. Marichal and J. Patarin, Dalton Trans., 2016, 45, 4392 DOI: 10.1039/C5DT03486H

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