Issue 3, 2016

A photo-induced C–C bond formation methodology to construct tetrahydrofluorenones and their related structures

Abstract

A metal-free, photo-induced C–C bond formation methodology was developed to construct tetrahydrofluorenones and their related structures. This mild and efficient method proceeds either through electrocyclization or radical cyclization from β-Cl or β-Br aryl vinyl ketone. We believe that this method is particularly useful for the synthesis of related tetrahydrofluorenone containing natural products.

Graphical abstract: A photo-induced C–C bond formation methodology to construct tetrahydrofluorenones and their related structures

Supplementary files

Article information

Article type
Research Article
Submitted
21 Xim 2015
Accepted
13 Qun 2016
First published
14 Qun 2016

Org. Chem. Front., 2016,3, 354-358

Author version available

A photo-induced C–C bond formation methodology to construct tetrahydrofluorenones and their related structures

S. Cai, Z. Xiao, J. Ou, Y. Shi and S. Gao, Org. Chem. Front., 2016, 3, 354 DOI: 10.1039/C5QO00392J

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