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In this Perspective article, recent advances in the chemistry of platinum group metal complexes containing mono- and dianionic guanidinate ligands, i.e. [(RN)2C–NR2] and [(RN)2C[double bond, length as m-dash]NR]2−, respectively, are presented. Synthetic and structural aspects, reactivity studies, and applications of these compounds are discussed.

Graphical abstract: The chemistry of guanidinate complexes of the platinum group metals

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