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We systematically studied the operation of coadsorber-induced surface chirality in a series of enantiomeric surface supramolecular assemblies. The correlation of chiral amplification degree with the proportion of enantiomeric interaction in the total intermolecular interaction is deduced.

Graphical abstract: Manifesting the sergeants-and-soldiers principle in coadsorber induced homochiral polymorphic assemblies at the liquid/solid interface

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