Issue 91, 2021

PN-Doped tetraphenylnaphthalene: a straightforward synthetic strategy analogous to BN-annulation

Abstract

Compared to BN heterocycles, few studies on PN heterocycles have been reported to date. Herein, we developed an efficient synthetic strategy analogous to BN-annulation to simultaneously incorporate a PN bond and a halogen group into the naphthalene core. Subsequently, we prepared PN-containing tetraphenylnaphthalene using this method, followed by palladium-catalyzed cross-coupling and reduction reactions. The prepared molecule was characterized via X-ray crystallography, NMR spectroscopy, UV-vis spectroscopy, and cyclic voltammetry.

Graphical abstract: PN-Doped tetraphenylnaphthalene: a straightforward synthetic strategy analogous to BN-annulation

Supplementary files

Article information

Article type
Communication
Submitted
27 avq 2021
Accepted
11 okt 2021
First published
11 okt 2021

Chem. Commun., 2021,57, 12147-12150

PN-Doped tetraphenylnaphthalene: a straightforward synthetic strategy analogous to BN-annulation

J. Park, S. J. Kim, H. Kwon, E. Jin, K. Yoon, H. Kim, S. Shadman, W. Choe, J. Kim and Y. S. Park, Chem. Commun., 2021, 57, 12147 DOI: 10.1039/D1CC04785J

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