Issue 41, 2023

Hydrogen peroxide photo-fuel cells

Abstract

Hydrogen peroxide (H2O2) possesses both strong oxidizing and moderate reducing ability. Due to the unique chemical reactivity, one-compartmentalization of fuel cells is possible by using H2O2 as both the fuel and oxidant for fuel cells (H2O2-FC). To enhance the anode reaction (H2O2 → O2 + 2H+ + 2e) of the H2O2-FC, a noble metal-free H2O2-photo fuel cell (PFC) has been newly developed for enhancing the conversion from chemical energy to electric energy with only emission of water and oxygen. The H2O2-photo fuel cells (PFC) take several significant advantages over the conventional hydrogen-oxygen fuel cells. With the realization of a solar-driven energy cycle with H2O2 as the key substance in mind, this Frontier article highlights the H2O2-PFCs. Firstly, the fundamentals of the H2O2-PFC are dealt with by treating the prototype using TiO2 as the photoanode. Then, recent progress in the H2O2-PFCs and an emerging application to self-powered biosensors are described. Finally, the conclusions are summarized with the future outlook.

Graphical abstract: Hydrogen peroxide photo-fuel cells

Article information

Article type
Frontier
Submitted
04 avq 2023
Accepted
07 sen 2023
First published
26 sen 2023

Dalton Trans., 2023,52, 14733-14741

Hydrogen peroxide photo-fuel cells

H. Tada, Dalton Trans., 2023, 52, 14733 DOI: 10.1039/D3DT02518G

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