Issue 33, 2008

Recent developments in the chemistry of low valent Group 14 hydrides

Abstract

This Perspective discusses the synthesis and reactivity of low valent Group 14 hydrides of germanium and tin. The use of hindered terphenyl ligands has facilitated the isolation of a number of unusual new main group hydride structural types (each predicted by computational work), and has culminated in the use of these species as precursors to new cluster archetypes.

Graphical abstract: Recent developments in the chemistry of low valent Group 14 hydrides

Article information

Article type
Perspective
Submitted
25 yan 2008
Accepted
03 mar 2008
First published
24 iyl 2008

Dalton Trans., 2008, 4336-4343

Recent developments in the chemistry of low valent Group 14 hydrides

E. Rivard and P. P. Power, Dalton Trans., 2008, 4336 DOI: 10.1039/B801400K

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