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Host-enhanced π–π interaction is employed as the driving force to construct supramolecular hyperbranched polymers. A three-arm monomer which possesses one naphthalene moiety in each arm has been designed and synthesised. Supramolecular hyperbranched polymers can be formed spontaneously by mixing the monomer and cucurbit[8]uril in 2 : 3 ratio.

Graphical abstract: Water-soluble supramolecular hyperbranched polymers based on host-enhanced π–π interaction

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