Design and synthesis of squaramide-based MOFs as efficient MOF-supported hydrogen-bonding organocatalysts

Xiaoping Zhang; Zhenjie Zhang; Jake Boissonnault; Seth M. Cohen

doi:10.1039/C6CC03190K

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Design and synthesis of squaramide-based MOFs as efficient MOF-supported hydrogen-bonding organocatalysts†

Xiaoping Zhang,‡^ab Zhenjie Zhang,‡^a Jake Boissonnault^a and Seth M. Cohen*^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA
E-mail: scohen@ucsd.edu

^b Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, P. R. China

Abstract

Herein, we utilize a new, squaramide-based ligand, combined with a postsynthetic exchange (PSE) synthetic approach to prepare a series of Cu(II)–squaramide MOFs that are active catalysts for the Friedel–Crafts reaction.

This article is part of the themed collection: Host–guest chemistry

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DOI: https://doi.org/10.1039/C6CC03190K
Article type: Communication
Submitted: 15 apr 2016
Accepted: 14 iyn 2016
First published: 14 iyn 2016
This article is Open Access

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Chem. Commun., 2016,52, 8585-8588

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Design and synthesis of squaramide-based MOFs as efficient MOF-supported hydrogen-bonding organocatalysts

X. Zhang, Z. Zhang, J. Boissonnault and S. M. Cohen, Chem. Commun., 2016, 52, 8585 DOI: 10.1039/C6CC03190K

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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Chemical Communications

Design and synthesis of squaramide-based MOFs as efficient MOF-supported hydrogen-bonding organocatalysts†

Abstract

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Design and synthesis of squaramide-based MOFs as efficient MOF-supported hydrogen-bonding organocatalysts

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