Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides

Yehong Wang; Jian Zhang; Haijun Chen; Zhixin Zhang; Chaofeng Zhang; Mingrun Li; Feng Wang

doi:10.1039/C6GC02603F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides†

Yehong Wang,^a Jian Zhang,^a Haijun Chen,^ab Zhixin Zhang,^a Chaofeng Zhang,^ab Mingrun Li^a and Feng Wang

*^a

Author affiliations

* Corresponding authors

^a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, 116023 Dalian, China
E-mail: wangfeng@dicp.ac.cn

^b University of the Chinese Academy of Sciences, 100049 Beijing, China

Abstract

We herein report a new strategy of directly converting amines and CO to formamides with 100% atom utilization efficiency. It is suitable for up to 25 amine substrates with no additives. Ru/ceria is found to be an excellent catalyst for this reaction due the efficient co-activation of CO and amine on Ru species.

This article is part of the themed collection: 2017 Green Chemistry Hot Articles

Download options Please wait...

Supplementary files

Supplementary information PDF (1003K)

Article information

DOI: https://doi.org/10.1039/C6GC02603F
Article type: Communication
Submitted: 17 sen 2016
Accepted: 13 okt 2016
First published: 14 okt 2016

Download Citation

Green Chem., 2017,19, 88-92

Permissions

Request permissions

Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides

Y. Wang, J. Zhang, H. Chen, Z. Zhang, C. Zhang, M. Li and F. Wang, Green Chem., 2017, 19, 88 DOI: 10.1039/C6GC02603F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Green Chemistry

Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides

Social activity

Search articles by author

Spotlight

Advertisements