Issue 4, 2018

Neutral two-dimensional organometallic–organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

Abstract

The reaction of the Pn ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with CuCl in the presence of 4,4′-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic–organic hybrid networks, the constitutional isomers [Cu2Cl2{Cp*Fe(μ35:1:1-P5)}(μ,η1:1-C10H8N2)]n (2 and 3) and the coordination polymer [(CuCl)2{Cp*Fe(μ35:1:1-P5)}(μ,η1:1-C12H10N2)]n (4) with isomeric square (2 and 3) and honeycomb (4) layer topologies.

Graphical abstract: Neutral two-dimensional organometallic–organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

Supplementary files

Article information

Article type
Communication
Submitted
13 noy 2017
Accepted
08 dek 2017
First published
08 dek 2017
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2018,47, 1014-1017

Neutral two-dimensional organometallic–organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

M. Elsayed Moussa, B. Attenberger, E. V. Peresypkina and M. Scheer, Dalton Trans., 2018, 47, 1014 DOI: 10.1039/C7DT04286H

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