Issue 45, 2019

A hybrid blue perovskite@metal–organic gel (MOG) nanocomposite: simultaneous improvement of luminescence and stability

Abstract

Blue light-emitting hybrid perovskite nanocrystals (NCs) are promising candidates for optoelectronic applications. However, these NCs suffer severely from low photoluminescence quantum yield (PLQY) and inferior stability under working conditions. Herein, we report, for the first time, a simultaneous dramatic improvement in both the luminescence and the stability of hybrid perovskite NCs through embedding in a porous metal–organic gel (MOG) matrix. The nanocomposite (EAPbBr3@MOG, EA: ethylammonium) shows sharp emission in the intense blue region (λmax < 440 nm), with a substantial ten-fold enhancement in the PLQY (∼53%) compared with EAPbBr3 NCs (PLQY ∼5%). Incorporation of perovskite NCs into the soft MOG matrix provides the additional benefits of flexibility as well as water stability. As a proof of principle, these nanocomposites were further utilized to fabricate a white light-emitting diode. The combination of high brightness, stability and flexibility of these nanocomposites could render them viable contenders in the development of efficient, blue light-emitting diodes for practical applications.

Graphical abstract: A hybrid blue perovskite@metal–organic gel (MOG) nanocomposite: simultaneous improvement of luminescence and stability

Associated articles

Supplementary files

Article information

Article type
Edge Article
Submitted
01 avq 2019
Accepted
24 sen 2019
First published
25 sen 2019
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2019,10, 10524-10530

A hybrid blue perovskite@metal–organic gel (MOG) nanocomposite: simultaneous improvement of luminescence and stability

S. Mollick, T. N. Mandal, A. Jana, S. Fajal and S. K. Ghosh, Chem. Sci., 2019, 10, 10524 DOI: 10.1039/C9SC03829A

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