Rim-differentiated Co-pillar[4+1]arenes†
Jianyi
Zhao, 
a
Weiwei
Yang,
a
Chuanyun
Liang,
a
Liya
Gao,
a
Jun
Xu,
a
Andrew C.-H.
Sue
*b
and
Hongxia
Zhao
*a
a
Weiwei
Yang,
a
Chuanyun
Liang,
a
Liya
Gao,
a
Jun
Xu,
a
Andrew C.-H.
Sue
*b
and
Hongxia
Zhao
*a
Abstract
A series of rim-differentiated Co-pillar[4+1]arenes featuring penta-substituted “upper” rims and mono-functionalisable “lower” rims was successfully synthesised and fully characterised. These novel pillar[5]arene-based scaffolds with clickable moieties and extra synthetic handles are versatile platforms for self-assembled molecular architectures and biological applications.
![Graphical abstract: Rim-differentiated Co-pillar[4+1]arenes](/az/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D1CC04840F&imageInfo.ImageIdentifier.Year=2021)
- This article is part of the themed collections: 2021 Emerging Investigators and Chemical Communications HOT articles
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