The rich physics of A-site-ordered quadruple perovskite manganites AMn7O12

Abstract

Perovskite-structure AMnO₃ manganites played an important role in the development of numerous physical concepts such as double exchange, small polarons, electron–phonon coupling, and Jahn–Teller effects, and they host a variety of important properties such as colossal magnetoresistance and spin-induced ferroelectric polarization (multiferroicity). A-site-ordered quadruple perovskite manganites AMn₇O₁₂ were discovered shortly after, but at that time their exploration was quite limited. Significant progress in their understanding has been reached in recent years after the wider use of high-pressure synthesis techniques needed to prepare such materials. Here we review this progress, and show that the AMn₇O₁₂ compounds host rich physics beyond the canonical AMnO₃ materials.