Black titania an emerging photocatalyst: review highlighting the synthesis techniques and photocatalytic activity for hydrogen generation

Abstract

The TiO₂ semiconductor photocatalyst is in the limelight of sustainable energy research in recent years because of its beneficial properties. However, its wide band-gap and rapid exciton recombination rate makes it a lame horse, and reduces its photocatalytic efficiency. Recently, researchers have developed facile methods for lowering the band-gap, so that it captures a wide range of solar spectrum, but the efficiency is still way behind the target value. After the discovery of black titania (B-TiO₂), the associated drawbacks of white TiO₂ and its modified forms were addressed to a large extent because it not only absorbs photons in a broad spectral range (UV to IR region), but also modifies the structural and morphological features, along with the electronic properties of the material, significantly boosting the catalytic performance. Hence, B-TiO₂ effectively converts solar energy into renewable chemical energy i.e. green fuel H₂ that can ultimately satisfy the energy crisis and environmental pollution. However, the synthesis techniques involved are quite tedious and challenging. Hence, this review summarizes various preparation methods of B-TiO₂ and the involved characterization techniques. It also discusses the different modification strategies adopted to improve the H₂ evolution activity, and hopes that this review acts as a guiding tool for researchers working in this field.