Photocatalytic stannylation of white phosphorus

Abstract

Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P₄) using a cheap, commercially-available distannane, (Bu₃Sn)₂, and anthraquinone as a simple photocatalyst. Subsequent ‘one pot’ transformation of the resulting stannylated monophosphine intermediate (Bu₃Sn)₃P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.