Issue 86, 2022

Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

Abstract

The solution-state structure of an amine-functionalised Cu24L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.

Graphical abstract: Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

Supplementary files

Article information

Article type
Communication
Submitted
08 sen 2022
Accepted
05 okt 2022
First published
06 okt 2022

Chem. Commun., 2022,58, 12122-12125

Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

M. L. Schneider, J. A. Campbell, A. D. Slattery and W. M. Bloch, Chem. Commun., 2022, 58, 12122 DOI: 10.1039/D2CC04969D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements