High Mg2+ conduction in three-dimensional pores of a metal–organic framework under organic vapors

Kouhei Aoki; Kenichi Kato; Masaaki Sadakiyo

doi:10.1039/D3DT00768E

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High Mg²⁺ conduction in three-dimensional pores of a metal–organic framework under organic vapors†

Kouhei Aoki,^a Kenichi Kato^b and Masaaki Sadakiyo

*^a

Author affiliations

* Corresponding authors

^a Department of Applied Chemistry, Faculty of Science Division I, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
E-mail: sadakiyo@rs.tus.ac.jp

^b RIKEN SPring-8 Center, Sayo-gun, Hyogo 679-5148, Japan

Abstract

We report on high Mg²⁺ conduction in a metal–organic framework (MOF), UiO-66, under organic vapors. We prepared a Mg²⁺-containing MOF, UiO-66⊃{Mg(TFSI)₂}_1.0 (TFSI⁻ = bis(trifluoromethanesulfonyl)imide), including Mg²⁺ carriers in three-dimensional pores. The compound showed a superionic conductivity above 10⁻⁴ S cm⁻¹ under MeCN and MeOH vapors.

This article is part of the themed collection: New Talent: Asia Pacific

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Article information

DOI: https://doi.org/10.1039/D3DT00768E
Article type: Communication
Submitted: 14 mar 2023
Accepted: 21 apr 2023
First published: 22 apr 2023
This article is Open Access

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Dalton Trans., 2023,52, 15313-15316

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High Mg²⁺ conduction in three-dimensional pores of a metal–organic framework under organic vapors

K. Aoki, K. Kato and M. Sadakiyo, Dalton Trans., 2023, 52, 15313 DOI: 10.1039/D3DT00768E

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