Overall structure of Au12Ag60(S-c-C6H11)31Br9(Dppp)6: achieving a stronger assembly of icosahedral M13 units

Abstract

Precise atomically assembled nanoclusters provide a great platform to elucidate the evolution of the assembly of building blocks. Herein, a large icosahedral (M₁₃)-based silver–gold alloy nanocluster [Au₁₂Ag₆₀(S-c-C₆H₁₁)₃₁Br₉(Dppp)₆]Br₂ (dppp = 1,3-bis(diphenylphosphino)propane) is reported. Structurally, Au₁₂Ag₆₀ consists of an Au₁₂Ag₄₀ kernel, which is viewed as the interpenetration of ten twisted complete icosahedrons (M₁₃) and two missing icosahedrons (M₁₂), and this is surrounded by a complex metal–organic shell. Benefiting from the extra doping of eight to twelve Au atoms, the octameric assembly was increased to a twelve-mer assembly. The time-dependent density functional theory (TDDFT) method with a Tamm–Dancoff approximation (TDA) was performed to investigate the difference in the optical properties of Au₁₂Ag₆₀ and Au₈Ag₅₇. The results indicate that the difference in the amount of Au atoms results in different optical properties. Furthermore, transient absorption spectroscopy (TA) was also performed, revealing that a twelve-mer assembly greatly enhances the excited-state lifetime. The [Au₁₂Ag₆₀(S-c-C₆H₁₁)₃₁Br₉(Dppp)₆]Br₂ alloy nanocluster has provided a breakthrough in the number of icosahedral M₁₃ assemblies, i.e., achieving a twelve-mer assembly, helping to elucidate the fusion growth of M₁₃-based assembled nanoclusters as well as their geometric/electronic structure correlations, which will promote further research on the assembly of M₁₃ nano-building blocks, especially on their optical properties.