Issue 8, 2023

Tunable Janus geometric morphology from aqueous two-phase systems on a superhydrophobic substrate

Abstract

Janus particles have garnered extensive attention owing to their considerable potential in the field of material engineering applications. Their properties are determined on the basis of the asymmetric structure or morphology. However, precisely engineering the morphology of Janus particles remains a grand challenge since the conventional preparation methods usually contain complicated dynamic processes. Herein, we report a facile route, which is wholly dependent on the thermodynamic characteristics of solution, to finely manipulate the morphologies of aqueous Janus droplets on a superhydrophobic surface. These Janus droplets contain polyethylene glycol (PEG) and dextran (DEX), and their Janus structures are controlled by the phase separation of the two polymers in aqueous solution. This phase separation procedure greatly relies on the molecular weight (MW) and concentration of PEG and DEX. As such, we can easily customize the morphology of the resultant Janus structure, including the Janus balance and curvature of the convex and concave phase interface, by varying those component inputs. This facile approach provides fresh insights into the tunable geometric morphology of Janus particles and holds potential applications in the preparation of asymmetric materials, particularly in biological fields.

Graphical abstract: Tunable Janus geometric morphology from aqueous two-phase systems on a superhydrophobic substrate

Supplementary files

Article information

Article type
Paper
Submitted
26 noy 2022
Accepted
17 yan 2023
First published
18 yan 2023

J. Mater. Chem. A, 2023,11, 4155-4161

Tunable Janus geometric morphology from aqueous two-phase systems on a superhydrophobic substrate

Q. Cheng, J. Chen, Y. Song, X. Yu, C. Guan, C. Wan, X. Tan and C. Huang, J. Mater. Chem. A, 2023, 11, 4155 DOI: 10.1039/D2TA09202F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements