Synthesis and soft crystal structure-induced broad emission of (NH3C6H12NH3)InBr5·2H2O

Shuva Biswas; Arnab Mandal; Diptikanta Swain; Kanishka Biswas

doi:10.1039/D4CC01822B

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Synthesis and soft crystal structure-induced broad emission of (NH₃C₆H₁₂NH₃)InBr₅·2H₂O†

Shuva Biswas,‡^a Arnab Mandal,‡^a Diptikanta Swain

^b and Kanishka Biswas

*^a

Author affiliations

* Corresponding authors

^a New Chemistry Unit, International Centre for Materials Science and School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur P. O., Bangalore 560064, India
E-mail: kanishka@jncasr.ac.in

^b Institute of Chemical Technology-IndianOil Odisha Campus, Bhubaneswar 751013, India

Abstract

We report a simple synthesis of a new lead-free zero-dimensional (0D) hybrid halide compound, (5P1)InBr₅·2H₂O [(5P1) = NH₃C₆H₁₂NH₃], which hosts isolated and distorted octahedra of [InBr₅(H₂O)]²⁻, surrounded by bulky asymmetric organic cations [(5P1)²⁺] and H₂O molecules. The hybrid crystals exhibit broad self trapped excitonic (STE) emission due to strong anharmonic soft structure.

This article is part of the themed collections: 2024 Pioneering Investigators and ChemComm 60th Anniversary Roadshow in India

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Article information

DOI: https://doi.org/10.1039/D4CC01822B
Article type: Communication
Submitted: 17 apr 2024
Accepted: 05 iyn 2024
First published: 06 iyn 2024

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Chem. Commun., 2024,60, 7757-7760

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Synthesis and soft crystal structure-induced broad emission of (NH₃C₆H₁₂NH₃)InBr₅·2H₂O

S. Biswas, A. Mandal, D. Swain and K. Biswas, Chem. Commun., 2024, 60, 7757 DOI: 10.1039/D4CC01822B

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