Recent advances in atomic cluster synthesis: a perspective from chemical elements

Abstract

Despite its potential significance, “cluster chemistry” remains a somewhat marginalized topic within the chemistry field. However, atomic clusters with their unusual and unique structures and properties represent a novel material group situated between molecules and nanoparticles or solid matter, judging from both scientific standpoints and historical backgrounds. Surveying an entire material group, including all substances that can be regarded as a cluster, is essential for establishing cluster chemistry as a more prominent chemistry field. This review aims to provide a comprehensive understanding by categorizing, summarizing, and reviewing clusters, focusing on their constituent elements in the periodic table. However, because numerous disparate synthetic processes have been individually developed to date, their straightforward and uniform classification is a challenging task. As such, comprehensively reviewing this field from a chemical composition viewpoint presents significant obstacles. It should be therefore noted that despite adopting a synthetic method-based classification in this review, the discussions presented herein could entail inaccuracies. Nevertheless, this unorthodox viewpoint unfolds a new scientific perspective which accentuates the common ground between different development processes by emphasizing the lack of a definitive border between their synthetic methods and material groups, thus opening new avenues for cementing cluster chemistry as an attractive chemistry field.