4f-Orbital mixing increases the magnetic susceptibility of Cp′3Eu

Abstract

Traditional models of lanthanide electronic structure suggest that bonding is predominantly ionic, and that covalent orbital mixing is not an important factor in determining magnetic properties. Here, 4f orbital mixing and its impact on the magnetic susceptibility of Cp′₃Eu (Cp′ = C₅H₄SiMe₃) was analyzed experimentally using magnetometry and X-ray absorption spectroscopy (XAS) methods at the C K-, Eu M_5,4-, and L₃-edges. Pre-edge features in the experimental and TDDFT-calculated C K-edge XAS spectra provided unequivocal evidence of C 2p and Eu 4f orbital mixing in the π-antibonding orbital of a′ symmetry. The charge-transfer configurations resulting from 4f orbital mixing were identified spectroscopically by using Eu M_5,4-edge and L₃-edge XAS. Modeling of variable-temperature magnetic susceptibility data showed excellent agreement with the XAS results and indicated that increased magnetic susceptibility of Cp′₃Eu is due to removal of the degeneracy of the ⁷F₁ excited state due to mixing between the ligand and Eu 4f orbitals.