Issue 8, 2024

Challenges and opportunities using Ni-rich layered oxide cathodes in Li-ion rechargeable batteries: the case of nickel cobalt manganese oxides

Abstract

This review provides an overview of recent advances in the utilization of Ni-rich nickel–cobalt–manganese (NCM) oxides as cathode materials for Li-ion rechargeable batteries (LIBs). In the past decade, Ni-rich NCM cathodes have been extensively investigated because of their rational capacity and easy accessibility of constituent elements. However, huge capacity fading and irreversible structural disorder, associated with oxygen release, are the major limitations which hinder the desired electrochemical performance of these cathodes. The LIB performance can be improved through several strategies such as doping, coating, composite formation, microstructure manipulation and replacing the Mn ions. Attempts are also made to amend the crystal orientation and achieve additive-induced surface engineering of NCM cathodes. However, the practical application of high-performance LIBs demand an effective modification of the intrinsic properties of NCMs. Substandard thermal stability is another safety aspect to be resolved in the Ni-rich NCMs. However, efforts in this context are not enough. Apart from designing NCM cathodes, there are major issues such as cost-effectiveness, supply and demand for constituent elements, and the reuse of spent batteries, which hinder the realisation of LIBs with high electrochemical performance. Keeping in mind the current research interests, this review article presents concise and in-depth strategies to design NCM cathodes for future energy demands of mankind by considering the cost and Co abundance-related issues.

Graphical abstract: Challenges and opportunities using Ni-rich layered oxide cathodes in Li-ion rechargeable batteries: the case of nickel cobalt manganese oxides

Article information

Article type
Review Article
Submitted
27 dek 2023
Accepted
19 iyn 2024
First published
10 iyl 2024
This article is Open Access
Creative Commons BY-NC license

Energy Adv., 2024,3, 1869-1893

Challenges and opportunities using Ni-rich layered oxide cathodes in Li-ion rechargeable batteries: the case of nickel cobalt manganese oxides

J. P. Singh, H. Devnani, A. Sharma, W. C. Lim, A. Dhyani, K. H. Chae and S. Lee, Energy Adv., 2024, 3, 1869 DOI: 10.1039/D3YA00631J

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements