Issue 71, 2002
From the journal:

CrystEngComm

Anion exchange in co-ordination polymers: a solid-state or a solvent-mediated process?†

Andrei N. Khlobystov,a   Neil R. Champness,*a   Clive J. Roberts,b   Saul J.B. Tendler,b   Claire Thompsonb  and  Martin Schröder*a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: neil.champness@nottingham.ac.uk, m.schroder@nottingham.ac.uk

b School of Pharmaceutical Sciences, University of Nottingham, University Park, Nottingham, UK

Abstract

Interconversion of chain co-ordination polymers {[Ag(4,4′-bipy)](X)}∞ (X = NO3− or BF4−) in aqueous media has been studied by IR and 1H NMR spectroscopy, transmission electron (TEM) and atomic force (AFM) microscopies and by X-ray powder diffraction (PXRD). The exchange leads to the formation of a pure crystalline phase of a new co-ordination polymer, and detailed TEM and AFM studies indicate a solvent-mediated rather than a solid-state mechanism for the exchange process.

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Article information

DOI
https://doi.org/10.1039/B202217F
Article type
Paper
Submitted
04 mar 2002
Accepted
01 may 2002
First published
19 iyl 2002

CrystEngComm, 2002,4, 426-431

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Anion exchange in co-ordination polymers: a solid-state or a solvent-mediated process?

A. N. Khlobystov, N. R. Champness, C. J. Roberts, S. J.B. Tendler, C. Thompson and M. Schröder, CrystEngComm, 2002, 4, 426 DOI: 10.1039/B202217F

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