Issue 58, 2014

Preparation of a “twisted basket” Mn4N8 cluster: a two-hydrogen-atom reduced analogue of the Mn4N8 pinned butterfly

Abstract

Mn4(μ-NHPh)4(μ-PhNNPh-κ2N,N′)2(py)4 (3) is synthesized via self assembly from dimeric Mn2(μ-NHPh)2(NR2)2 and PhNHNHPh (R = SiMe3). This cluster represents the N–N cleaved version of the previously-reported Mn4(μ-NHPh)23-PhNNPh-κ3N,N′)2(μ-PhNNPh-κ2N,N′)(py)4 “pinned butterfly” cluster (2), formally reduced by two hydrogen atoms. Cluster 2 may be converted to 3 by addition of N,N′-diphenylhydrazine as a two-electron reductant.

Graphical abstract: Preparation of a “twisted basket” Mn4N8 cluster: a two-hydrogen-atom reduced analogue of the Mn4N8 pinned butterfly

Supplementary files

Article information

Article type
Communication
Submitted
18 apr 2014
Accepted
15 may 2014
First published
16 may 2014

Chem. Commun., 2014,50, 7780-7782

Preparation of a “twisted basket” Mn4N8 cluster: a two-hydrogen-atom reduced analogue of the Mn4N8 pinned butterfly

M. R. Gau, C. R. Hamilton and M. J. Zdilla, Chem. Commun., 2014, 50, 7780 DOI: 10.1039/C4CC02872D

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