This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.
Lite Version|Standard version
Home > Chemical Communications >
To gain access to this content please
Log in via your home Institution.
Log in with your member or subscriber username and password.
Download


Buy PDF Add PDF to Basket (£42,50*)
*Exclusive of taxes
This article contains 4 page(s)
Abstract | Cited by

A new rotor exhibits rich solvatomorphism behavior with eight X-ray structures obtained. A heterogeneous solid obtained by mechanical stress exhibited a dominant isotropic 2H line shape at high temperatures. The motion occurs only in the amorphous component of this solid, with an Ea of 7.4 kcal mol−1 and a low pre-exponential factor A of 6.22 × 1010 s−1, which indicates that the motion requires the distortion of the molecular axis.

Graphical abstract: Triggering the dynamics of a carbazole-p-[phenylene-diethynyl]-xylene rotor through a mechanically induced phase transition

Page: ^ Top


Enter Keywords, author, title,reference, or DOI
Log in | Register