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We demonstrate that tetra-arm poly(ethylene glycol) gels containing highly concentrated sulfolane-based electrolytes exhibit high Li+ transference numbers. The low polymer concentration and homogeneous polymer network in the gel electrolyte are useful in achieving both mechanical reliability and high Li+ transport ability.

Graphical abstract: Tetra-arm poly(ethylene glycol) gels with highly concentrated sulfolane-based electrolytes exhibiting high Li-ion transference numbers

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