Pyridine synthesis from oximes and alkynesviarhodium(III) catalysis: Cp* and Cpt provide complementary selectivity

Todd K. Hyster; Tomislav Rovis

doi:10.1039/C1CC15248C

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Pyridine synthesis from oximes and alkynesviarhodium(iii) catalysis: Cp* and Cp^t provide complementary selectivity†‡

Todd K. Hyster^a and Tomislav Rovis*^a

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* Corresponding authors

^a Department of Chemistry, Colorado State University, Fort Collins
E-mail: rovis@lamar.colostate.edu
Fax: (+1) 970-491-1801
Tel: (+1) 970-491-7208

Abstract

The synthesis of pyridines from readily available α,β-unsaturated oximes and alkynes under mild conditions and low temperatures using Rh(III) catalysis has been developed. It was found that the use of sterically different ligands allows for complementary selectivities to be achieved.

This article is part of the themed collection: New advances in catalytic C–C bond formation via late transition metals

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Correction: Pyridine synthesis from oximes and alkynes via rhodium(iii) catalysi…

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Article information

DOI: https://doi.org/10.1039/C1CC15248C
Article type: Communication
Submitted: 23 Aug 2011
Accepted: 21 Sep 2011
First published: 10 Oct 2011

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Chem. Commun., 2011,47, 11846-11848

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Pyridine synthesis from oximes and alkynesviarhodium(III) catalysis: Cp* and Cp^t provide complementary selectivity

T. K. Hyster and T. Rovis, Chem. Commun., 2011, 47, 11846 DOI: 10.1039/C1CC15248C

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