Issue 78, 2014
From the journal:

Chemical Communications

Organic azides: “energetic reagents” for the intermolecular amination of C–H bonds

Daniela Intrieri,a   Paolo Zardi,a   Alessandro Casellia  and  Emma Gallo*a  

* Corresponding authors

a Università degli Studi di Milano - Chemistry Department, Via Golgi 19, 20136 Milano, Italy
E-mail: emma.gallo@unimi.it
Fax: +39 (0)2 50314405
Tel: +39 (0)2 50314374

Abstract

This feature article provides an overview of the application of organic azides for the intermolecular amination of sp3 and sp2 C–H bonds. The catalytic activity of several metal complexes was reviewed underlining both synthetic and mechanistic aspects of the C–H amination. The majority of the aminated compounds reported in literature have been collected in this paper to provide a compendium of published procedures. In addition, the discussion of involved mechanisms has been included to assist the reader to envisage the future potential of organic azides in the synthesis of aza-derivatives.

Graphical abstract: Organic azides: “energetic reagents” for the intermolecular amination of C–H bonds

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Article information

DOI
https://doi.org/10.1039/C4CC03016H
Article type
Feature Article
Submitted
23 Apr 2014
Accepted
23 May 2014
First published
27 May 2014
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 11440-11453

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Organic azides: “energetic reagents” for the intermolecular amination of C–H bonds

D. Intrieri, P. Zardi, A. Caselli and E. Gallo, Chem. Commun., 2014, 50, 11440 DOI: 10.1039/C4CC03016H

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