Issue 100, 2016
From the journal:

Chemical Communications

[{β-SiNi2W10O36(OH)2(H2O)}4]24−: a new robust visible light-driven water oxidation catalyst based on nickel-containing polyoxometalate†

Li Yu,a   Yong Ding,*ab   Min Zheng,a   Hongli Chena  and  Junwei Zhaoc  

* Corresponding authors

a Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
E-mail: dingyong1@lzu.edu.cn

b State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, China

c Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, P. R. China

Abstract

[{β-SiNi2W10O36(OH)2(H2O)}4]24− (1) was reported as efficient, robust visible light-driven water oxidation catalyst for the first time. Of the reported polyoxometalates containing nickel, 1 shows the best photocatalytic O2 evolution activity with a TON of 335 and TOF of 1.7 s−1.

Graphical abstract: [{β-SiNi2W10O36(OH)2(H2O)}4]24−: a new robust visible light-driven water oxidation catalyst based on nickel-containing polyoxometalate

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Article information

DOI
https://doi.org/10.1039/C6CC02728H
Article type
Communication
Submitted
31 Mar 2016
Accepted
18 Apr 2016
First published
18 Apr 2016

Chem. Commun., 2016,52, 14494-14497

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[{β-SiNi2W10O36(OH)2(H2O)}4]24−: a new robust visible light-driven water oxidation catalyst based on nickel-containing polyoxometalate

L. Yu, Y. Ding, M. Zheng, H. Chen and J. Zhao, Chem. Commun., 2016, 52, 14494 DOI: 10.1039/C6CC02728H

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