Issue 1, 2017
From the journal:

CrystEngComm

Comment on “1,4-Diazabicyclo[2.2.2]octane-based disalts showing non-centrosymmetric structures and phase transition behaviors” by X.-B. Han, P. Hu, C. Shi and W. Zhang, CrystEngComm, 2016, 18, 1563†

Marek Szafrańskia  

a Faculty of Physics, Adam Mickiewicz University, Umultowska 85, 61-614 Poznań, Poland
E-mail: masza@amu.edu.pl

Abstract

This Letter is in response to a paper by Han et al. (CrystEngComm, 2016, 18, 1563–1569) on the structures and isostructural phase transitions in (dabcoH2)(BF4)2·H2O and (dabcoH2)(ClO4)2·H2O. It is shown that the phase transitions in these compounds have a second-order character and their low-temperature phases exhibit ferroelastic properties. Thus, the transitions cannot be isostructural. The redeterminations of both crystal structures as a function of temperature evidence that at the transition points the symmetry is reduced from orthorhombic to triclinic.

Graphical abstract: Comment on “1,4-Diazabicyclo[2.2.2]octane-based disalts showing non-centrosymmetric structures and phase transition behaviors” by X.-B. Han, P. Hu, C. Shi and W. Zhang, CrystEngComm, 2016, 18, 1563

About
Cited by
Related
Download options Please wait...

Associated articles

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6CE01469K
Article type
Letter
Submitted
30 Jun 2016
Accepted
23 Nov 2016
First published
08 Dec 2016

CrystEngComm, 2017,19, 179-182

Permissions

Request permissions

Comment on “1,4-Diazabicyclo[2.2.2]octane-based disalts showing non-centrosymmetric structures and phase transition behaviors” by X.-B. Han, P. Hu, C. Shi and W. Zhang, CrystEngComm, 2016, 18, 1563

M. Szafrański, CrystEngComm, 2017, 19, 179 DOI: 10.1039/C6CE01469K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements