Solution-phase syntheses of three bioactive natural products of mixed polypeptide–polyketide biogenesis, fellutamides A, B, and C, have been achieved. Three peptide bonds are generated without the use of coupling reagents in each synthesis of the fellutamides, which act against proteasomes.
M. C. Pirrung, F. Zhang, S. Ambadi and Y. Gangadhara Rao, Org. Biomol. Chem., 2016, 14, 8367 DOI: 10.1039/C6OB01233G
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