Synthesis of a Fe3O4@P4VP@metal–organic framework core–shell structure and studies of its aerobic oxidation reactivity

Zongcheng Miao; Xin Shu; Daniele Ramella

doi:10.1039/C6RA25820D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Synthesis of a Fe₃O₄@P4VP@metal–organic framework core–shell structure and studies of its aerobic oxidation reactivity†

Zongcheng Miao,^a Xin Shu

*^b and Daniele Ramella^c

Author affiliations

* Corresponding authors

^a Xijing University, Xi'an, Shaanxi Province, P. R. China

^b College of Science, Beijing University of Chemical Technology, Beijing 100029, P. R. China
E-mail: shuxin@mail.buct.edu.cn

^c Temple University-Beury Hall, 1901, N. 13th Street, Philadelphia, PA 19122, USA

Abstract

A novel core–shell magnetic Fe₃O₄@P4VP(poly(4-vinylpyridine))@MIL-100(Fe) composite material has been successfully synthesized. The Fe₃O₄@P4VP core was initially prepared via polymerization of P4VP on the surface of pre-made Fe₃O₄ microspheres. The MIL-100(Fe) (MIL, Matérial Institut Lavoisier) metal–organic framework shell was then introduced through a layer by layer strategy. The obtained Fe₃O₄@P4VP@MIL-100(Fe) catalyst was applied in the selective oxidation of alcohols using molecular oxygen as the oxidant, and a variety of substrates were tolerated. The initial activity of the Fe₃O₄@P4VP@MIL-100(Fe) core–shell catalyst was maintained after ten reuses.

Download options Please wait...

Associated articles

Expression of concern: Synthesis of a Fe3O4@P4VP@metal–organic framework core–sh…

Supplementary files

Supplementary information PDF (552K)

Article information

DOI: https://doi.org/10.1039/C6RA25820D
Article type: Paper
Submitted: 25 Oct 2016
Accepted: 12 Dec 2016
First published: 12 Jan 2017
This article is Open Access

Download Citation

RSC Adv., 2017,7, 2773-2779

Permissions

Request permissions

Synthesis of a Fe₃O₄@P4VP@metal–organic framework core–shell structure and studies of its aerobic oxidation reactivity

Z. Miao, X. Shu and D. Ramella, RSC Adv., 2017, 7, 2773 DOI: 10.1039/C6RA25820D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Social activity

Fetching data from CrossRef.
This may take some time to load.

RSC Advances