Laser printing of optically resonant hollow crystalline carbon nanostructures from 1D and 2D metal–organic frameworks†
Andrei A.
Krasilin, 
b
Pavel
Trofimov,
b
Evgeniy V.
Ubyivovk,
c
Thierry
Belmonte
e
and
Valentin A.
Milichko
*b
b
Pavel
Trofimov,
b
Evgeniy V.
Ubyivovk,
c
Thierry
Belmonte
e
and
Valentin A.
Milichko
*b
Abstract
Using a hybrid approach involving a slow diffusion method to synthesize 1D and 2D MOFs followed by their treatment with femtosecond infrared laser radiation, we generated 100–600 nm well-defined hollow spheres and hemispheres of graphite. This ultra-fast technique extends the library of shapes of crystalline MOF derivatives appropriate for all-dielectric nanophotonics.
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