Generally, Eu²⁺ doped multi-site phosphors have more effective luminescent centers (m) than lattice sites (M), and the luminescence spectra would be greatly enriched if m is infinitely close or even equal to M. Herein, a series of Eu²⁺ doped Ca₉La_1−xM_1.5x(PO₄)₇ (M = Mg, Ca, Sr, or Ba) phosphors with adjusted output color were reported for the first time, in which new luminescence centers were successfully monitored using bivalent alkaline earth metal ions as inducing factors. The variation of cell parameters and component contents confirms the substitution of La³⁺ sites with six coordination by the inducing ions. After excluding the possibility of defective luminescence by thermoluminescence spectra, Eu³⁺ ions are used as lattice probes to prove that Eu²⁺ activated in six coordinates is the cause of new emission center, in which the decisive role of the inducing factors is elaborately discussed. The results open an effective avenue for spectral adjustment in multi-site phosphors via artificially inducing potential luminescence centers.