Issue 74, 2020
From the journal:

Chemical Communications

Thermo- and electro-switchable Cs⊂{Fe4–Fe4} cubic cage: spin-transition and electrochromism†

Jana Glatz,a   Lise-Marie Chamoreau,a   Alexandrine Flambard,a   Jean-Francois Meunier,b   Azzedine Bousseksoub  and  Rodrigue Lescouëzec ORCID logo *a  

* Corresponding authors

a Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Sorbonne Université, 4 place Jussieu, 750005 Paris, France
E-mail: rodrigue.lescouezec@sorbonne-universite.fr

b Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse, France
E-mail: azzedine.bousseksou@lcc-toulouse.fr

Abstract

A mixed valence Cs⊂{Fe4–Fe4} cyanido-cube was synthesized and structurally characterized. The molecule, which is robust in solution, shows remarkable electronic versatility. Electrochromic properties associated with nine different electronic states are observed in solution together with a thermo-induced spin-transition in the solid state.

Graphical abstract: Thermo- and electro-switchable Cs⊂{Fe4–Fe4} cubic cage: spin-transition and electrochromism

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Article information

DOI
https://doi.org/10.1039/D0CC04279J
Article type
Communication
Submitted
19 Jun 2020
Accepted
05 Aug 2020
First published
11 Aug 2020

Chem. Commun., 2020,56, 10950-10953

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Thermo- and electro-switchable Cs⊂{Fe4–Fe4} cubic cage: spin-transition and electrochromism

J. Glatz, L. Chamoreau, A. Flambard, J. Meunier, A. Bousseksou and R. Lescouëzec, Chem. Commun., 2020, 56, 10950 DOI: 10.1039/D0CC04279J

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