Issue 23, 2020

Visible-light-mediated borylation of aryl and alkyl halides with a palladium complex

Abstract

Palladium catalyzed visible-light-mediated borylation of inactivated aryl and alkyl halides is reported; the method provided high yields and excellent functional group compatibility. Furthermore, arylsilicates were synthesized selectively using dimethylphenylsilyl boronic ester via changing the reaction conditions. Finally, the possible reaction mechanism is determined through fluorescence quenching and turn on/off experiments.

Graphical abstract: Visible-light-mediated borylation of aryl and alkyl halides with a palladium complex

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
06 Jan 2020
Accepted
13 May 2020
First published
14 May 2020

Org. Biomol. Chem., 2020,18, 4390-4394

Visible-light-mediated borylation of aryl and alkyl halides with a palladium complex

J. Zhao, Z. Zhou, Y. Zhang, X. Su, X. Chen and Y. Liang, Org. Biomol. Chem., 2020, 18, 4390 DOI: 10.1039/D0OB00028K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements