Retracted Article: CoH-catalyzed radical hydroalkylation of alkenes with 1,3-dicarbonyls

Meihui Guan; Huanran Miao; Tao Qin; Ge Zhang; Qian Zhang

doi:10.1039/D2CC01382G

Retracted Article: CoH-catalyzed radical hydroalkylation of alkenes with 1,3-dicarbonyls†

Meihui Guan,^a Huanran Miao,^a Tao Qin,^a Ge Zhang*^a and Qian Zhang

*^ab

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* Corresponding authors

^a Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, Changchun 130024, China
E-mail: zhangg492@nenu.edu.cn, zhangq651@nenu.edu.cn

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China

Abstract

Metal-hydride hydrogen atom transfer (MHAT) catalysis has emerged as a useful reaction platform for alkene hydrofunctionalization with high chemoselectivity and predictable branched selectivity. However, MHAT-mediated hydrofunctionalization involves carbon–carbon bond formation still confined to carbon electrophiles. Here, we describe a mild, general, scalable, and functional group tolerant CoH-catalyzed intermolecular hydroalkylation of alkenes with 1,3-dicarbonyls. This kind of CoH-catalyzed coupling of alkenes with carbon nucleophiles represents an important complement to the arsenal of MHAT-initiated hydrofunctionalization of alkenes.

Chemical Communications

Retracted Article: CoH-catalyzed radical hydroalkylation of alkenes with 1,3-dicarbonyls†

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